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THE HALOALKANES
The haloalkanes (also known as halogenoalkanes or alkyl halides) are a group of chemical compounds derived from alkanes containing one or more halogens. They are a subset of the general class of halocarbons, although the distinction is not often made. Haloalkanes are widely used commercially and, consequently, are known under many chemical and commercial names. They are used as flame retardants, fire extinguishants, refrigerants, propellants, solvents, and pharmaceuticals. Subsequent to the widespread use in commerce, many halocarbons have also been shown to be serious pollutants and toxins. For example, the chlorofluorocarbons have been shown to lead to ozone depletion. Methyl bromide is a controversial fumigant. Only haloalkanes which contain chlorine, bromine, and iodine are a threat to the ozone layer, but fluorinated volatile haloalkanes in theory may have activity as greenhouse gases. For more information, see Halon.
Haloalkanes have been known for centuries. Ethyl chloride was produced synthetically in the 15th century. The systematic synthesis of such compounds developed in the 19th century in step with the development of organic chemistry and the understanding of the structure of alkanes. Methods were developed for the selective formation of C-halogen bonds. Especially versatile methods included the addition of halogens to alkenes, hydrohalogenation of alkenes, and the conversion of alcohols to alkyl halides. These methods are so reliable and so easily implemented that haloalkanes became cheaply available for use in industrial chemistry because the halide could be further replaced by other functional groups.
While most haloalkanes are human-produced, non-artificial-source haloalkanes do occur on Earth, mostly through enzyme-mediated synthesis by bacteri, fungi, and especially sea macroalgae (seaweeds). More than 1600 halogenated organics have been identified, with bromoalkanes being the most common haloalkanes. Brominated organics in biology range from biologically-produced methyl bromide to non-alkane aromatics and unsaturates (indoles, terpenes, acetogenins, and phenols).[1] [2] Halogenated alkanes in land plants are more rare, but do occur, as for example the fluoroacetate produced as a toxin by at least 40 species of known plants. Specific dehalogenase enzymes in bacteria which remove halogens from haloalkanes, are also known.
From the structural perspective, haloalkanes can be classified according to the connectivity of the carbon atom to which the halogen is attached. In primary (1°) haloalkanes, the carbon that carries the halogen atom is only attached to one other alkyl group. An example is 1-chloroethane (CH3CH2Cl). In secondary (2°) haloalkanes, the carbon that carries the halogen atom has two C-C bonds. In tertiary (3°) haloalkanes, the carbon that carries the halogen atom has three C-C bonds.
Haloalkanes can also be classified according to the type of halogen. Haloalkanes containing carbon bonded to fluorine, chlorine, bromine, and iodine results in organofluorine, organochlorine, organobromine and organoiodine compounds, respectively. Compounds containing more than one kind of halogen are also possible, the best-known examples being the chlorofluorocarbons (CFCs).
[edit] Properties
Haloalkanes generally resemble the parent alkanes in being colorless, relatively odorless, and hydrophobic. Their boiling points are higher than the corresponding alkanes and scale with the atomic weight and number of halides. This is due to the increased strength of the intermolecular forces—from London dispersion to dipole-dipole interaction because of the increased polarity. Thus CI4 is a solid whereas CF4 is a gas. As they contain fewer C-H bonds, halocarbons are less flammable than alkanes, and some are used in fire extinguishers. Haloalkanes are better solvents than the corresponding alkanes because of their increased polarity. Haloalkanes are uniformly more reactive than the parent alkanes - it is this reactivity that is the basis of most controversies. Many are alkylating agents. The ozone-depleting abilities of the CFC's arises from the photolability of the C-Cl bond.
[edit] Occurrence
Haloalkanes are of wide interest because they are widespread and have diverse beneficial and detrimental impacts. The oceans are estimated to release 1-2 million tons of bromomethane annually.[3]
A large number of pharmaceuticals contain halogens, especially fluorine. An estimated one fifth of pharmaceuticals contain fluorine, including several of the top drugs.[4] Examples include 5-fluorouracil, fluoxetine (Prozac), paroxetine (Paxil), ciprofloxacin (Cipro), mefloquine, and fluconazole. The beneficial effects arise because the C-F bond is relatively unreactive. Fluorine-substituted ethers are volatile anesthetics, including the commercial products methoxyflurane, enflurane, isoflurane, sevoflurane and desflurane. Fluorocarbon anesthetics reduce the hazard of flammability with diethyl ether and cyclopropane. Perfluorinated alkanes are used as blood substitutes.
Teflon structure
Chlorinated or fluorinated alkenes undergo polymerization. Important halogenated polymers include polyvinyl chloride (PVC), and polytetrafluoroethene (PTFE, or Teflon). The production of these materials releases substantial amounts of wastes.
[edit] Nomenclature
[edit] IUPAC
The formal naming of haloalkanes should follow IUPAC nomenclature, which put the halogen as a prefix to the alkane. For example, ethane with bromine becomes bromoethane, methane with four chlorine groups becomes tetrachloromethane. However, many of these compounds have already an established trivial name, which is endorsed by the IUPAC nomenclature, for example chloroform (trichloromethane) and methylene chloride (dichloromethane). For unambiguity, this article follows the systematic naming scheme throughout.
[edit] Production
Haloalkanes can be produced from virtually all organic precursors. From the perspective of industry, the most important ones are alkanes and alkenes.
[edit] From alkanes
Main article: Free radical halogenation
Alkanes react with halogens by free radical halogenation. In this reaction a hydrogen atom is removed from the alkane, then replaced by a halogen atom by reaction with a diatomic halogen molecule. The reactive intermediate in this reaction is a free radical and the reaction is called a radical chain reaction.
Free radical halogenation typically produces a mixture of compounds mono- or multihalogenated at various positions. It is possible to predict the results of a halogenation reaction based on bond dissociation energies and the relative stabilities of the radical intermediates. Another factor to consider is the probability of reaction at each carbon atom, from a statistical point of view.
Due to the different dipole moments of the product mixture, it may be possible to separate them by distillation.
[edit] From alkenes and alkynes
In hydrohalogenation, an alkene reacts with a dry hydrogen halide (HX) like hydrogen chloride (HCl) or hydrogen bromide (HBr) to form a mono-haloalkane. The double bond of the alkene is replaced by two new bonds, one with the halogen and one with the hydrogen atom of the hydrohalic acid. Markovnikov's rule states that in this reaction, the halogen is more likely to become attached to the more substituted carbon. This is a electrophilic addition reaction. Water must be absent otherwise there will be a side product of a halohydrin. The reaction is necessarily to be carried out in a dry inert solvent such as CCl4 or directly in the gaseous phase. The reaction of alkynes are similar, with the product being a geminal dihalide; once again, Markovnikov's rule is followed.
Alkenes also react with halogens (X2) to form haloalkanes with two neighboring halogen atoms in a halogen addition reaction. Alkynes react similarly, forming the tetrahalo compounds. This is sometimes known as "decolorizing" the halogen, since the reagent X2 is colored and the product is usually colorless.
[edit] From alcohols
Tertiary alkanol reacts with hydrochloric acid directly to produce tertiary chloroalkane, but if primary or secondary alkanol is used, an activator such as zinc chloride is needed. This reaction is exploited in the Lucas test.
The most popular conversion is effected by reacting the alcohol with thionyl chloride in the "Darzen's process," which is one of the most convenient laboratory methods because the byproducts are gaseous. Both phosphorus pentachloride (PCl5) and phosphorus trichloride (PCl3) also convert the hydroxyl group to the chloride.
Alcohol may likewise be converted to bromoalkane using hydrobromic acid or phosphorus tribromide (PBr3). A catalytic amount of PBr3 may be used for the transformation using phosphorus and bromine; PBr3 is formed in situ. Iodoalkanes may similarly be prepared using using red phosphorus and iodine (equivalent to phosphorus triiodide). The Appel reaction is also useful for preparing alkyl halides. The reagent is tetrahalomethane and triphenylphosphine; the co-products are haloform and triphenylphosphine oxide.
[edit] From carboxylic acids
Two methods for the synthesis of alkyl halides from carboxylic acids are the Hunsdiecker reaction and the Kochi reaction.
[edit] Biosynthesis
Many chloro and bromolkanes are formed naturally. The principal pathways involve the enzymes chloroperoxidase and bromoperoxidase.
[edit] Reactions
Haloalkanes are reactive towards nucleophiles. They are polar molecules: the carbon to which the halogen is attached is slightly electropositive where the halogen is slightly electronegative. This results in an electron deficient (electrophilic) carbon which, inevitably, attracts nucleophiles.
[edit] Substitution
Substitution reactions involve the replacement of the halogen with another molecule - thus leaving saturated hydrocarbons, as well as the halogenated product. Alkyl halides behave as the R+ synthon, and readily react with nucleophiles.
Hydrolysis - a reaction in which water breaks a bond - is a good example of the nucleophilic nature of halogenoalkanes. The polar bond attracts a hydroxide ion, OH-. (NaOH(aq) being a common source of this ion). This OH- is a nucleophile with a clearly negative charge, as it has excess electrons it donates them to the carbon, which results in a covalent bond between the two. Thus C-X is broken by heterolytic fission resulting in a halide ion, X-. As can be seen, the OH is now attached to the alkyl group, creating an alcohol. (Hydrolysis of bromoethane, for example, yields ethanol). Reaction with ammonia give primary amines.
Alkyl chlorides and bromides are readily substituted by iodide in the Finkelstein reaction. The alkyl iodides produced easily undergo further reaction. Sodium iodide is used thus as a catalyst. Alkyl halides react with ionic nucleophiles (e.g. cyanide, thiocyanate, azide); the halogen is replaced by the respective group. This is of great synthetic utility: alkyl chlorides are often inexpensively available. For example, after undergoing substitution reactions, alkyl cyanides may be hydrolyzed to carboxylic acids, or reduced to primary amines using lithium aluminium hydride. Alkyl azides may be reduced to primary alkyl amines by the Staudinger reduction or lithium aluminium hydride. Amines may also be prepared from alkyl halides in amine alkylation, the Gabriel synthesis and Delepine reaction, by undergoing nucleophilic substitution with potassium phthalimide or hexamine respectively, followed by hydrolysis.
In the presence of a base, alky halides alkylate alcohols, amines, and thiols to obtain ethers, N-substituted amines, and thioethers respectively. They are substituted by Grignard reagents to give magnesium salts and an extended alkyl compound.
[edit] Mechanism
Where the rate-determining step of a nucleophilic substitution reaction is unimolecular, it is known as an SN1 reaction. In this case, the slowest (thus rate-determining step) is the heterolysis of a carbon-halogen bond to give a carbocation and the halide anion. The nucleophile (electron doner) attacks the carbocation to give the product.
SN1 reactions are associated with the racemization of the compound, as the trigonal planar carbocation may be attacked from either face. They are favored mechanism for tertiary alkyl halides, due to the stabilization of the positive charge on the carbocation by three electron-donating alkyl groups. They are also preferred where the substituents are sterically bulky, hindering the SN2 mechanism.
[edit] Elimination
Main article: Dehydrohalogenation
Rather than creating a molecule with the halogen substituted with something else, one can completely eliminate both the halogen and a nearby hydrogen, thus forming an alkene by dehydrohalogenation. For example, with bromoethane and sodium hydroxide (NaOH) in ethanol, the hydroxide ion HO- abstracts a hydrogen atom. Bromide ion is then lost, resulting in ethylene), H2O and NaBr. Thus, haloalkanes can be converted to alkenes. Similarly, dihaloalkanes can be converted to alkynes.
In related reactions, 1,2-dibromocompounds are debrominated by zinc dust to give alkenes and geminal dihalides can react with strong bases to give carbenes.
[edit] Other
Alkyl halides undergo free-radical reactions with elemental magnesium to give alkylmagnesium compounds: Grignard reagents. Alkyl halides also react with lithium metal to give organolithium compounds. Both Grignard reagents and organolithium compounds behave as the R- synthon. Alkali metals such as sodium and lithium are able to cause alkyl halides to couple in the Wurtz reaction, giving symmetrical alkanes. Alkyl halides, especially iodides, also undergo oxidative addition reactions to give organometallic compounds.
[edit] Applications
Haloalkanes are widely used as synthon equivalents to alkyl cation (R+) in organic synthesis. They can also participate in a wide variety of other organic reactions.
Short chain haloalkanes such as dichloromethane, trichloromethane (chloroform) and tetrachloromethane are commonly used as hydrophobic solvents in chemistry.
Chlorofluorocarbons have also been widely used as refrigerants, propellants and solvents due to their low toxicity and high heat capacity.for more click here
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THE HALOALKANES
The haloalkanes (also known as halogenoalkanes or alkyl halides) are a group of chemical compounds derived from alkanes containing one or more halogens. They are a subset of the general class of halocarbons, although the distinction is not often made. Haloalkanes are widely used commercially and, consequently, are known under many chemical and commercial names. They are used as flame retardants, fire extinguishants, refrigerants, propellants, solvents, and pharmaceuticals. Subsequent to the widespread use in commerce, many halocarbons have also been shown to be serious pollutants and toxins. For example, the chlorofluorocarbons have been shown to lead to ozone depletion. Methyl bromide is a controversial fumigant. Only haloalkanes which contain chlorine, bromine, and iodine are a threat to the ozone layer, but fluorinated volatile haloalkanes in theory may have activity as greenhouse gases. For more information, see Halon.
Haloalkanes have been known for centuries. Ethyl chloride was produced synthetically in the 15th century. The systematic synthesis of such compounds developed in the 19th century in step with the development of organic chemistry and the understanding of the structure of alkanes. Methods were developed for the selective formation of C-halogen bonds. Especially versatile methods included the addition of halogens to alkenes, hydrohalogenation of alkenes, and the conversion of alcohols to alkyl halides. These methods are so reliable and so easily implemented that haloalkanes became cheaply available for use in industrial chemistry because the halide could be further replaced by other functional groups.
While most haloalkanes are human-produced, non-artificial-source haloalkanes do occur on Earth, mostly through enzyme-mediated synthesis by bacteri, fungi, and especially sea macroalgae (seaweeds). More than 1600 halogenated organics have been identified, with bromoalkanes being the most common haloalkanes. Brominated organics in biology range from biologically-produced methyl bromide to non-alkane aromatics and unsaturates (indoles, terpenes, acetogenins, and phenols).[1] [2] Halogenated alkanes in land plants are more rare, but do occur, as for example the fluoroacetate produced as a toxin by at least 40 species of known plants. Specific dehalogenase enzymes in bacteria which remove halogens from haloalkanes, are also known.
From the structural perspective, haloalkanes can be classified according to the connectivity of the carbon atom to which the halogen is attached. In primary (1°) haloalkanes, the carbon that carries the halogen atom is only attached to one other alkyl group. An example is 1-chloroethane (CH3CH2Cl). In secondary (2°) haloalkanes, the carbon that carries the halogen atom has two C-C bonds. In tertiary (3°) haloalkanes, the carbon that carries the halogen atom has three C-C bonds.
Haloalkanes can also be classified according to the type of halogen. Haloalkanes containing carbon bonded to fluorine, chlorine, bromine, and iodine results in organofluorine, organochlorine, organobromine and organoiodine compounds, respectively. Compounds containing more than one kind of halogen are also possible, the best-known examples being the chlorofluorocarbons (CFCs).
[edit] Properties
Haloalkanes generally resemble the parent alkanes in being colorless, relatively odorless, and hydrophobic. Their boiling points are higher than the corresponding alkanes and scale with the atomic weight and number of halides. This is due to the increased strength of the intermolecular forces—from London dispersion to dipole-dipole interaction because of the increased polarity. Thus CI4 is a solid whereas CF4 is a gas. As they contain fewer C-H bonds, halocarbons are less flammable than alkanes, and some are used in fire extinguishers. Haloalkanes are better solvents than the corresponding alkanes because of their increased polarity. Haloalkanes are uniformly more reactive than the parent alkanes - it is this reactivity that is the basis of most controversies. Many are alkylating agents. The ozone-depleting abilities of the CFC's arises from the photolability of the C-Cl bond.
[edit] Occurrence
Haloalkanes are of wide interest because they are widespread and have diverse beneficial and detrimental impacts. The oceans are estimated to release 1-2 million tons of bromomethane annually.[3]
A large number of pharmaceuticals contain halogens, especially fluorine. An estimated one fifth of pharmaceuticals contain fluorine, including several of the top drugs.[4] Examples include 5-fluorouracil, fluoxetine (Prozac), paroxetine (Paxil), ciprofloxacin (Cipro), mefloquine, and fluconazole. The beneficial effects arise because the C-F bond is relatively unreactive. Fluorine-substituted ethers are volatile anesthetics, including the commercial products methoxyflurane, enflurane, isoflurane, sevoflurane and desflurane. Fluorocarbon anesthetics reduce the hazard of flammability with diethyl ether and cyclopropane. Perfluorinated alkanes are used as blood substitutes.
Teflon structure
Chlorinated or fluorinated alkenes undergo polymerization. Important halogenated polymers include polyvinyl chloride (PVC), and polytetrafluoroethene (PTFE, or Teflon). The production of these materials releases substantial amounts of wastes.
[edit] Nomenclature
[edit] IUPAC
The formal naming of haloalkanes should follow IUPAC nomenclature, which put the halogen as a prefix to the alkane. For example, ethane with bromine becomes bromoethane, methane with four chlorine groups becomes tetrachloromethane. However, many of these compounds have already an established trivial name, which is endorsed by the IUPAC nomenclature, for example chloroform (trichloromethane) and methylene chloride (dichloromethane). For unambiguity, this article follows the systematic naming scheme throughout.
[edit] Production
Haloalkanes can be produced from virtually all organic precursors. From the perspective of industry, the most important ones are alkanes and alkenes.
[edit] From alkanes
Main article: Free radical halogenation
Alkanes react with halogens by free radical halogenation. In this reaction a hydrogen atom is removed from the alkane, then replaced by a halogen atom by reaction with a diatomic halogen molecule. The reactive intermediate in this reaction is a free radical and the reaction is called a radical chain reaction.
Free radical halogenation typically produces a mixture of compounds mono- or multihalogenated at various positions. It is possible to predict the results of a halogenation reaction based on bond dissociation energies and the relative stabilities of the radical intermediates. Another factor to consider is the probability of reaction at each carbon atom, from a statistical point of view.
Due to the different dipole moments of the product mixture, it may be possible to separate them by distillation.
[edit] From alkenes and alkynes
In hydrohalogenation, an alkene reacts with a dry hydrogen halide (HX) like hydrogen chloride (HCl) or hydrogen bromide (HBr) to form a mono-haloalkane. The double bond of the alkene is replaced by two new bonds, one with the halogen and one with the hydrogen atom of the hydrohalic acid. Markovnikov's rule states that in this reaction, the halogen is more likely to become attached to the more substituted carbon. This is a electrophilic addition reaction. Water must be absent otherwise there will be a side product of a halohydrin. The reaction is necessarily to be carried out in a dry inert solvent such as CCl4 or directly in the gaseous phase. The reaction of alkynes are similar, with the product being a geminal dihalide; once again, Markovnikov's rule is followed.
Alkenes also react with halogens (X2) to form haloalkanes with two neighboring halogen atoms in a halogen addition reaction. Alkynes react similarly, forming the tetrahalo compounds. This is sometimes known as "decolorizing" the halogen, since the reagent X2 is colored and the product is usually colorless.
[edit] From alcohols
Tertiary alkanol reacts with hydrochloric acid directly to produce tertiary chloroalkane, but if primary or secondary alkanol is used, an activator such as zinc chloride is needed. This reaction is exploited in the Lucas test.
The most popular conversion is effected by reacting the alcohol with thionyl chloride in the "Darzen's process," which is one of the most convenient laboratory methods because the byproducts are gaseous. Both phosphorus pentachloride (PCl5) and phosphorus trichloride (PCl3) also convert the hydroxyl group to the chloride.
Alcohol may likewise be converted to bromoalkane using hydrobromic acid or phosphorus tribromide (PBr3). A catalytic amount of PBr3 may be used for the transformation using phosphorus and bromine; PBr3 is formed in situ. Iodoalkanes may similarly be prepared using using red phosphorus and iodine (equivalent to phosphorus triiodide). The Appel reaction is also useful for preparing alkyl halides. The reagent is tetrahalomethane and triphenylphosphine; the co-products are haloform and triphenylphosphine oxide.
[edit] From carboxylic acids
Two methods for the synthesis of alkyl halides from carboxylic acids are the Hunsdiecker reaction and the Kochi reaction.
[edit] Biosynthesis
Many chloro and bromolkanes are formed naturally. The principal pathways involve the enzymes chloroperoxidase and bromoperoxidase.
[edit] Reactions
Haloalkanes are reactive towards nucleophiles. They are polar molecules: the carbon to which the halogen is attached is slightly electropositive where the halogen is slightly electronegative. This results in an electron deficient (electrophilic) carbon which, inevitably, attracts nucleophiles.
[edit] Substitution
Substitution reactions involve the replacement of the halogen with another molecule - thus leaving saturated hydrocarbons, as well as the halogenated product. Alkyl halides behave as the R+ synthon, and readily react with nucleophiles.
Hydrolysis - a reaction in which water breaks a bond - is a good example of the nucleophilic nature of halogenoalkanes. The polar bond attracts a hydroxide ion, OH-. (NaOH(aq) being a common source of this ion). This OH- is a nucleophile with a clearly negative charge, as it has excess electrons it donates them to the carbon, which results in a covalent bond between the two. Thus C-X is broken by heterolytic fission resulting in a halide ion, X-. As can be seen, the OH is now attached to the alkyl group, creating an alcohol. (Hydrolysis of bromoethane, for example, yields ethanol). Reaction with ammonia give primary amines.
Alkyl chlorides and bromides are readily substituted by iodide in the Finkelstein reaction. The alkyl iodides produced easily undergo further reaction. Sodium iodide is used thus as a catalyst. Alkyl halides react with ionic nucleophiles (e.g. cyanide, thiocyanate, azide); the halogen is replaced by the respective group. This is of great synthetic utility: alkyl chlorides are often inexpensively available. For example, after undergoing substitution reactions, alkyl cyanides may be hydrolyzed to carboxylic acids, or reduced to primary amines using lithium aluminium hydride. Alkyl azides may be reduced to primary alkyl amines by the Staudinger reduction or lithium aluminium hydride. Amines may also be prepared from alkyl halides in amine alkylation, the Gabriel synthesis and Delepine reaction, by undergoing nucleophilic substitution with potassium phthalimide or hexamine respectively, followed by hydrolysis.
In the presence of a base, alky halides alkylate alcohols, amines, and thiols to obtain ethers, N-substituted amines, and thioethers respectively. They are substituted by Grignard reagents to give magnesium salts and an extended alkyl compound.
[edit] Mechanism
Where the rate-determining step of a nucleophilic substitution reaction is unimolecular, it is known as an SN1 reaction. In this case, the slowest (thus rate-determining step) is the heterolysis of a carbon-halogen bond to give a carbocation and the halide anion. The nucleophile (electron doner) attacks the carbocation to give the product.
SN1 reactions are associated with the racemization of the compound, as the trigonal planar carbocation may be attacked from either face. They are favored mechanism for tertiary alkyl halides, due to the stabilization of the positive charge on the carbocation by three electron-donating alkyl groups. They are also preferred where the substituents are sterically bulky, hindering the SN2 mechanism.
[edit] Elimination
Main article: Dehydrohalogenation
Rather than creating a molecule with the halogen substituted with something else, one can completely eliminate both the halogen and a nearby hydrogen, thus forming an alkene by dehydrohalogenation. For example, with bromoethane and sodium hydroxide (NaOH) in ethanol, the hydroxide ion HO- abstracts a hydrogen atom. Bromide ion is then lost, resulting in ethylene), H2O and NaBr. Thus, haloalkanes can be converted to alkenes. Similarly, dihaloalkanes can be converted to alkynes.
In related reactions, 1,2-dibromocompounds are debrominated by zinc dust to give alkenes and geminal dihalides can react with strong bases to give carbenes.
[edit] Other
Alkyl halides undergo free-radical reactions with elemental magnesium to give alkylmagnesium compounds: Grignard reagents. Alkyl halides also react with lithium metal to give organolithium compounds. Both Grignard reagents and organolithium compounds behave as the R- synthon. Alkali metals such as sodium and lithium are able to cause alkyl halides to couple in the Wurtz reaction, giving symmetrical alkanes. Alkyl halides, especially iodides, also undergo oxidative addition reactions to give organometallic compounds.
[edit] Applications
Haloalkanes are widely used as synthon equivalents to alkyl cation (R+) in organic synthesis. They can also participate in a wide variety of other organic reactions.
Short chain haloalkanes such as dichloromethane, trichloromethane (chloroform) and tetrachloromethane are commonly used as hydrophobic solvents in chemistry.
Chlorofluorocarbons have also been widely used as refrigerants, propellants and solvents due to their low toxicity and high heat capacity.for more click here
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By Gregory Chapman
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Cloth interior is less expensive than leather, and for a shopper on a budget this would be the way to go. Another advantage of choosing this interior is that it can be more comfortable, especially for kids. Young kids often fall asleep in car rides, and the cloth interior is comfortable to sleep on. The interior absorbs sweat and will not make you perspire. If you live in a really hot climate this will be advantageous for you especially if you do not like to sweat. Another great advantage of cloth interior is that the temperature of your car seats will not be extremely hot or cold. The cloth holds the same temperature.
On the other hand, a lot of people prefer a leather interior. If you are buying rel=nofollow [http://www.gregchapmanmotors.com/]Austin used cars, this interior can increase the value of your vehicle. Leather has more of a luxurious appearance and is very comfortable to sit on. Another great advantage is that it is very easy to clean. Liquid cannot be absorbed into the material and you will not have to worry about your car or truck smelling bad. You can even purchase leather interior treatment products from your car dealer. Because leather does not absorb odors, the smell of your car will always be good.
There are advantages with both types of interiors. The type you choose should be about your personal preferences. After looking at the benefits of both interiors, you should be able to make a choice that is best for you and your driving needs.
You may be in the market for purchasing a vehicle. There are so many things to consider and a lot of research should be done before making your final purchase. Some factors you may consider are: do you want a car or a truck or an SUV, new or used, black or blue, leather or cloth, and many more factors. Some people prefer to be an impulse shopper, but when it comes to automobiles you should take the time to research your purchase. Used car dealers are great resources and do not be afraid to ask questions from your dealer.
Once you have narrowed down your choices, you should then decide on the interior you want for your vehicle. One interior may be better in certain climates, and one may be beneficial for your needs. Fortunately, this choice does not have to be too time consuming because your choices are leather or cloth. Here are some of the advantages of each to help you in making your decision. You can weigh out the advantages of each and see which interior will best suit your needs.
Cloth interior is less expensive than leather, and for a shopper on a budget this would be the way to go. Another advantage of choosing this interior is that it can be more comfortable, especially for kids. Young kids often fall asleep in car rides, and the cloth interior is comfortable to sleep on. The interior absorbs sweat and will not make you perspire. If you live in a really hot climate this will be advantageous for you especially if you do not like to sweat. Another great advantage of cloth interior is that the temperature of your car seats will not be extremely hot or cold. The cloth holds the same temperature.
On the other hand, a lot of people prefer a leather interior. If you are buying rel=nofollow [http://www.gregchapmanmotors.com/]Austin used cars, this interior can increase the value of your vehicle. Leather has more of a luxurious appearance and is very comfortable to sit on. Another great advantage is that it is very easy to clean. Liquid cannot be absorbed into the material and you will not have to worry about your car or truck smelling bad. You can even purchase leather interior treatment products from your car dealer. Because leather does not absorb odors, the smell of your car will always be good.
There are advantages with both types of interiors. The type you choose should be about your personal preferences. After looking at the benefits of both interiors, you should be able to make a choice that is best for you and your driving needs.
Posted by
science mix
comments (0)
By Gregory Chapman
You may be in the market for purchasing a vehicle. There are so many things to consider and a lot of research should be done before making your final purchase. Some factors you may consider are: do you want a car or a truck or an SUV, new or used, black or blue, leather or cloth, and many more factors. Some people prefer to be an impulse shopper, but when it comes to automobiles you should take the time to research your purchase. Used car dealers are great resources and do not be afraid to ask questions from your dealer.
Once you have narrowed down your choices, you should then decide on the interior you want for your vehicle. One interior may be better in certain climates, and one may be beneficial for your needs. Fortunately, this choice does not have to be too time consuming because your choices are leather or cloth. Here are some of the advantages of each to help you in making your decision. You can weigh out the advantages of each and see which interior will best suit your needs.
Cloth interior is less expensive than leather, and for a shopper on a budget this would be the way to go. Another advantage of choosing this interior is that it can be more comfortable, especially for kids. Young kids often fall asleep in car rides, and the cloth interior is comfortable to sleep on. The interior absorbs sweat and will not make you perspire. If you live in a really hot climate this will be advantageous for you especially if you do not like to sweat. Another great advantage of cloth interior is that the temperature of your car seats will not be extremely hot or cold. The cloth holds the same temperature.
On the other hand, a lot of people prefer a leather interior. If you are buying rel=nofollow [http://www.gregchapmanmotors.com/]Austin used cars, this interior can increase the value of your vehicle. Leather has more of a luxurious appearance and is very comfortable to sit on. Another great advantage is that it is very easy to clean. Liquid cannot be absorbed into the material and you will not have to worry about your car or truck smelling bad. You can even purchase leather interior treatment products from your car dealer. Because leather does not absorb odors, the smell of your car will always be good.
There are advantages with both types of interiors. The type you choose should be about your personal preferences. After looking at the benefits of both interiors, you should be able to make a choice that is best for you and your driving needs.
You may be in the market for purchasing a vehicle. There are so many things to consider and a lot of research should be done before making your final purchase. Some factors you may consider are: do you want a car or a truck or an SUV, new or used, black or blue, leather or cloth, and many more factors. Some people prefer to be an impulse shopper, but when it comes to automobiles you should take the time to research your purchase. Used car dealers are great resources and do not be afraid to ask questions from your dealer.
Once you have narrowed down your choices, you should then decide on the interior you want for your vehicle. One interior may be better in certain climates, and one may be beneficial for your needs. Fortunately, this choice does not have to be too time consuming because your choices are leather or cloth. Here are some of the advantages of each to help you in making your decision. You can weigh out the advantages of each and see which interior will best suit your needs.
Cloth interior is less expensive than leather, and for a shopper on a budget this would be the way to go. Another advantage of choosing this interior is that it can be more comfortable, especially for kids. Young kids often fall asleep in car rides, and the cloth interior is comfortable to sleep on. The interior absorbs sweat and will not make you perspire. If you live in a really hot climate this will be advantageous for you especially if you do not like to sweat. Another great advantage of cloth interior is that the temperature of your car seats will not be extremely hot or cold. The cloth holds the same temperature.
On the other hand, a lot of people prefer a leather interior. If you are buying rel=nofollow [http://www.gregchapmanmotors.com/]Austin used cars, this interior can increase the value of your vehicle. Leather has more of a luxurious appearance and is very comfortable to sit on. Another great advantage is that it is very easy to clean. Liquid cannot be absorbed into the material and you will not have to worry about your car or truck smelling bad. You can even purchase leather interior treatment products from your car dealer. Because leather does not absorb odors, the smell of your car will always be good.
There are advantages with both types of interiors. The type you choose should be about your personal preferences. After looking at the benefits of both interiors, you should be able to make a choice that is best for you and your driving needs.
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By Max Bellamy
The car seat industry has seen unprecedented growth in the past few years, even as its prices are getting a bit higher. Now that consumers are giving placing more value on comfort and durability, they don't mind paying more.
If you are one such discriminating consumer, then you should know exactly how the most comfortable car seats are made and what they are made of. Read this short article and be guided when you shop for your next car seats.
The comfort and durability of a car seat depends on the quality and engineering of its four major components: backrest, cushion-spring platform, upholstery, and padding materials. Modern car seats (especially those used in higher-end sedans and SUVs) combine these four elements not only to create attractive silhouettes, but more importantly, to produce ergonomic and safe car seats.
Ergonomic car seats are great for vehicles used for long driving. Some very good car seats are pressurized to conform to the natural shape of every body type so that the passenger's back, neck, and hips are amply supported.
A lot of consumers don't realize it, but a good car seat can save lives, especially in rear collision instances. Structurally safe seats have special metal structures that absorb impact so that the backrest remains sturdy during collision and the safety belt can function to its fullest. Top-quality car seats are usually subjected to rigorous safety tests before they are released to the market, so if you can afford to spend a bit more, you should definitely consider buying them.
Material is likewise an important consideration when choosing car seats, because it determines how long the units will last. More expensive cars seats typically use hard-wearing fibers or soft but durable leather materials. Stitching is important, too - and this is where handmade car seats lead. Handmade car seats are processed very carefully so that every stitch is perfect and every curve is superbly secured.
The car seat industry has seen unprecedented growth in the past few years, even as its prices are getting a bit higher. Now that consumers are giving placing more value on comfort and durability, they don't mind paying more.
If you are one such discriminating consumer, then you should know exactly how the most comfortable car seats are made and what they are made of. Read this short article and be guided when you shop for your next car seats.
The comfort and durability of a car seat depends on the quality and engineering of its four major components: backrest, cushion-spring platform, upholstery, and padding materials. Modern car seats (especially those used in higher-end sedans and SUVs) combine these four elements not only to create attractive silhouettes, but more importantly, to produce ergonomic and safe car seats.
Ergonomic car seats are great for vehicles used for long driving. Some very good car seats are pressurized to conform to the natural shape of every body type so that the passenger's back, neck, and hips are amply supported.
A lot of consumers don't realize it, but a good car seat can save lives, especially in rear collision instances. Structurally safe seats have special metal structures that absorb impact so that the backrest remains sturdy during collision and the safety belt can function to its fullest. Top-quality car seats are usually subjected to rigorous safety tests before they are released to the market, so if you can afford to spend a bit more, you should definitely consider buying them.
Material is likewise an important consideration when choosing car seats, because it determines how long the units will last. More expensive cars seats typically use hard-wearing fibers or soft but durable leather materials. Stitching is important, too - and this is where handmade car seats lead. Handmade car seats are processed very carefully so that every stitch is perfect and every curve is superbly secured.
Posted by
science mix
comments (0)
By Max Bellamy
The car seat industry has seen unprecedented growth in the past few years, even as its prices are getting a bit higher. Now that consumers are giving placing more value on comfort and durability, they don't mind paying more.
If you are one such discriminating consumer, then you should know exactly how the most comfortable car seats are made and what they are made of. Read this short article and be guided when you shop for your next car seats.
The comfort and durability of a car seat depends on the quality and engineering of its four major components: backrest, cushion-spring platform, upholstery, and padding materials. Modern car seats (especially those used in higher-end sedans and SUVs) combine these four elements not only to create attractive silhouettes, but more importantly, to produce ergonomic and safe car seats.
Ergonomic car seats are great for vehicles used for long driving. Some very good car seats are pressurized to conform to the natural shape of every body type so that the passenger's back, neck, and hips are amply supported.
A lot of consumers don't realize it, but a good car seat can save lives, especially in rear collision instances. Structurally safe seats have special metal structures that absorb impact so that the backrest remains sturdy during collision and the safety belt can function to its fullest. Top-quality car seats are usually subjected to rigorous safety tests before they are released to the market, so if you can afford to spend a bit more, you should definitely consider buying them.
Material is likewise an important consideration when choosing car seats, because it determines how long the units will last. More expensive cars seats typically use hard-wearing fibers or soft but durable leather materials. Stitching is important, too - and this is where handmade car seats lead. Handmade car seats are processed very carefully so that every stitch is perfect and every curve is superbly secured.
The car seat industry has seen unprecedented growth in the past few years, even as its prices are getting a bit higher. Now that consumers are giving placing more value on comfort and durability, they don't mind paying more.
If you are one such discriminating consumer, then you should know exactly how the most comfortable car seats are made and what they are made of. Read this short article and be guided when you shop for your next car seats.
The comfort and durability of a car seat depends on the quality and engineering of its four major components: backrest, cushion-spring platform, upholstery, and padding materials. Modern car seats (especially those used in higher-end sedans and SUVs) combine these four elements not only to create attractive silhouettes, but more importantly, to produce ergonomic and safe car seats.
Ergonomic car seats are great for vehicles used for long driving. Some very good car seats are pressurized to conform to the natural shape of every body type so that the passenger's back, neck, and hips are amply supported.
A lot of consumers don't realize it, but a good car seat can save lives, especially in rear collision instances. Structurally safe seats have special metal structures that absorb impact so that the backrest remains sturdy during collision and the safety belt can function to its fullest. Top-quality car seats are usually subjected to rigorous safety tests before they are released to the market, so if you can afford to spend a bit more, you should definitely consider buying them.
Material is likewise an important consideration when choosing car seats, because it determines how long the units will last. More expensive cars seats typically use hard-wearing fibers or soft but durable leather materials. Stitching is important, too - and this is where handmade car seats lead. Handmade car seats are processed very carefully so that every stitch is perfect and every curve is superbly secured.